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原位复合法制备含稀土铕(Ⅲ)配合物光学树脂及其荧光性质的研究 被引量:3

Synthesis and Luminescence Properties of Optical Resins Containing Europium(Ⅲ) Complex by in situ Composite Method
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摘要 采用原位复合的方法,使多种稀土铕(Ⅲ)的配合物在聚合反应的过程中形成。同时,分别考察了不同配体和惰性离子Y3+对光学树脂荧光性质的影响。结果表明:采用原位复合的方法获得的含稀土铕(Ⅲ)配合物光学树脂的荧光强度要高于掺杂法制备含稀土配合物的光学树脂,其荧光寿命也更长。 The optical resin containing many kind of rare earth europium complexes were obtained by in situ composite method, in which rare earth complexes were synthesized in the polymerization process. The relationship between the fluorescence property of optical resin and the kinds of organic ligands, and inertia yttrium (Ⅲ) in copolymerization system were investigated. The results indicate that optical resin by in situ method show stronger emission intensities and longer lifetime than optical resin by incorporate method.
出处 《中国稀土学报》 CAS CSCD 北大核心 2002年第6期663-666,共4页 Journal of the Chinese Society of Rare Earths
基金 国家自然科学基金资助项目(200340062 29925412)
关键词 原位复合法 制备 稀土 铕(Ⅲ)配合物 光学树脂 复合材料 甲基丙烯酸 苯乙烯 rare earths in situ composite optical resin luminescent properties
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  • 1Yan B, Zhang H, Wang S, et al. Luminescence properties of rare earth (Eu3+ and Tb3+) complexes with paraaminobenzoic Acid and 1,10-Phenanthroline incorporated into a silica matrix by Sol-Gel method [J]. Materials Research Bulletin, 1998, 33(10): 1517.
  • 2Lu Hong, Li Gaofen, Fang Shibi, et al. Fluorescent properties of polymer rare earth ion complexesⅡ poly (acrylic acid-co-acrylamide)-rare earth ion complexes [J]. J. Appl. Poly. Sci., 1990, 39: 1389.
  • 3Yang Y S, Gang M L, Li Y Y, et al. Effects of the structure of ligands and their Ln3+ complexes on the luminescence of the central Ln3+ ions [J]. Journal of Alloys and Compounds, 1994, 207/208: 112
  • 4林权,庄儒田,张先念,杨柏.甲基丙烯酸镉的共聚合及其光学性能研究[J].高分子学报,1999,9(2):189-193. 被引量:11
  • 5汪联辉,章文贡.含烷氧基钕共聚物的合成及其光学性质[J].高等学校化学学报,1996,17(5):808-811. 被引量:17
  • 6Banks E, Okamoto Y, Ueba Y. Synthesis and characterization of rare earth metel containing plymers I. Fluorescent properties of ionomers containing Dy3+, Er3+, Eu3+ and Sm3+ [J]. J. Appl. Polym. Sci., 1980, 25(2): 359.
  • 7Ueba Y, Banks E, Okamoto Y. Investigation on the synthesis and characterization of rare earth metal-containing polymers Ⅱ [J]. J. Appl. Polym. Sci., 1980, 25(12): 2007.
  • 8Okamoto Y, Ueba Y, Nagata I, et al. Rare earth metel containing polymers 4. Energy transfer from uranyl to europium ion in ionomers [J]. Macromolecules, 1981, (14): 807.
  • 9Wang Y P, Lei Z Q, Feng H Y, et al. Synthesis and fluorescence properties of rare earth metal ion-polymer ligand-low molecular weight ligand ternary complexes [J]. J. Appl. Poly. Sci., 1992, 45: 1641.
  • 10李文连.稀土有机电致发光研究进展[J].中国稀土学报,1999,17(3):267-270. 被引量:30

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