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类Salen和β-二酮钆(Ⅲ)配合物的合成和晶体结构（英文） 被引量：1

Synthesis and crystal structure of a salen-type andβ-diketionate Gd_2 complex
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摘要 通过配体1,3-苯二胺缩邻香兰素和Gd(acac)_3·H_2O反应,合成了一个双核稀土配合物[Gd_2L(acac)_4(CH_3OH)]_4·3CH_2Cl_2(1),X-射线单晶衍射分析确定了该配合物的晶体结构,配合物中两个钆(Ⅲ)离子具有相同的配位构型,均为8配位的反四棱柱构型。 A dinuclear lanthanide complex [Gd2L(acac)4 (CH3OH)]4 · 3CH2Cl2 (1)supported by salen‐type (H2 L = N , N′‐bis (2‐oxy‐3‐methoxybenzylidene)‐1 , 2‐phenylenediamine) ligand and Gd(acac)3 · H2 O (acac = acetylacetonate) is structurally characterized .X‐ray crystallographic analysis reveals that two Gd (III) ions adopt the same coordination environments that the octacoordinated Gd(III) atoms are in a square antiprism geometry .
作者 邹晓艳 闫鹏飞 董艳萍 李光明
机构地区 黑龙江大学<黑龙江大学工程学报>编辑部 黑龙江大学功能无机材料化学省部共建教育部重点实验室 黑龙江大学化学化工与材料学院
出处 《黑龙江大学工程学报》 2015年第4期27-31,共5页 Journal of Engineering of Heilongjiang University
基金 国家自然科学基金资助项目(51402092) 黑龙江省普通本科高等学校青年创新人才培养计划(UNPYSCT-2015113)
关键词 1 3-苯二胺缩邻香兰素 Β-二酮 钆(Ⅲ)配合物 配位 N,N′-bis(2-oxy-3-methoxybenzylidene)-1,2-phenylenediamine β-diketonate Gd(Ⅲ) complex coordination
分类号 O641.4 [理学—物理化学]
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参考文献22

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二级参考文献18

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共引文献3

同被引文献17

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黑龙江大学工程学报
2015年 第4期

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