铜离子选择电极间接测定微量钍

INDIRECT DETERMINATION OF THORIUM USING CUPRIC ION SELECTIVE ELECTRODE

具有实用意义的钍离子选择电极,至今未见报道。1974年,有人利用Th4+与F-生成稳定络合物,用氟离子选择电极测出与Th4+络合的F-量,间接知道Th4+量。分析下限为2×10-5M,相对误差为2％。

A method is described for the indirect determination of thorium using cupric ion selective electrode. The method is based on the reaction Th4+ +Cu2+-EDTA Th4+-EDTA+Cu2+The cupric ion is determined by using cupric ion selective electrode, and then the concentration of the thorium ion is known since it is equal to the concentration of the cupric ion.The medium is 0.2M NaNO3 (pH=5.0-5.5). The following ions do not interfere: Mg2+, Ca2+, Mn2+, A13+, Co2+, Ni2+, Cl-, SO2- and macro-amount of U (Ⅵ). The sensitivity of the method is 1×10-6M, and the precision of the determination is better than 5%.The method is simple, rapid and suitable for the determination of micro-amount of thorium in a solution containing macro-amount of uranium.