期刊文献+

在多元醇体系中一锅法合成具有良好储锂性能的介孔碳-锡复合材料 被引量:1

One-pot Synthesis of Sn/Mesoporous Carbon Composite in a Polyol System with Well-improved Lithium Storage Capability
原文传递
导出
摘要 以介孔碳(MC)为导电和支撑介质,在多元醇体系中通过简便的化学还原方法制备纳米结构的介孔碳-锡(MC-Sn)复合材料.采用扫描电子显微镜(SEM)、高分辨透射电子显微镜(HRTEM)和恒电流充放电实验对所得产物的形貌、结构及电化学性能进行表征.结果表明,大量的Sn纳米颗粒均匀且致密地附着在介孔碳上.作为锂离子电池负极材料,MC-Sn复合物表现出了较好的循环性能和倍率性能.例如,在100 m A·g-1的充放电速率下循环40圈,其放电比容量保持在721.5 m Ah·g-1;当充放电速率增大到1 A·g-1时,其放电比容量仍高达265.8 m Ah·g-1.简单的制备方法和优越的储锂性能,使得MC-Sn复合材料成为一种理想的高性能锂离子电池负极材料. By introducing three-dimensional mesoporous carbon(MC) as a conducting and buffering matrix, MC-Sn composite has been synthesized through a facile chemical reduction approach in a polyol system at the temperature of 170 ℃ which is protected by nitrogen atmosphere. Pure Sn nanoparticles were synthesized through the same methodology, but without the addition of MC. The morphology, structure and electrochemical performance of the products have been characterized by scanning electron microscopy(SEM), high-resolution transmission electron microscopy(HRTEM), and constant current discharge/charge tests. It is indicated that numerous Sn nanoparticles have been uniformly and densely decorated on the MC matrix. When evaluated as an anode material for lithium-ion batteries(LIBs), the as-prepared MC-Sn composite exhibits markedly improved cycling stability and rate capability compared to pure Sn nanoparticles. For example, a high discharge capacity of 721.5 m Ah·g-1 can be retained after 40 discharge/charge cycles at a current density of 100 m A·g-1 in the potential range of 0.01~2 V. When tested under the same condition, pure Sn nanoparticles remain only 361.7 m Ah·g-1. The rate capability of MC-Sn composite was examined in comparison with pure Sn nanoparticles at various current densities from 100 to 200, 500 and 1000 m A·g-1. The MC-Sn composite delivers a discharge capacity of 760.5 m Ah·g-1 at a current density of 100 m A·g-1 after 10 cycles. This value decreases to 555.6 m Ah·g-1(200 m A·g-1), 366.2 m Ah·g-1(500 m A· g-1), 265.8 m Ah·g-1(1000 m A·g-1), and finally returns to 684.3 m Ah·g-1 at 100 m A·g-1. In sharp contrast, the discharge capacities of pure Sn nanoparticles decrease rapidly with the increase of current densities. These results demonstrate that the MC-Sn composite possesses markedly improved rate capability, making it a promising anode for LIBs with high power densities.
出处 《化学学报》 SCIE CAS CSCD 北大核心 2015年第2期151-155,共5页 Acta Chimica Sinica
基金 江苏省产学研前瞻性研究(No.BY2013001-01) 江苏省自然科学基金(No.BK20130900) 江苏省高校自然科学基金(No.13KJB150026) 南京师范大学高层次人才启动基金(No.2013103XGQ0008) 江苏高校优势学科建设工程项目资助~~
关键词 锂离子电池 负极材料 介孔碳-锡 多元醇 化学还原法 lithium-ion batteries anode materials MC-Sn polyol system chemical reduction approach
  • 相关文献

参考文献17

  • 1Jizhang Chen,Li Yang,Shaohua Fang,Zhengxi Zhang,Aniruddha Deb,Shin-ichi Hirano.Sn-contained N-rich carbon nanowires for high-capacity and long-life lithium storage[J]. Electrochimica Acta . 2014
  • 2Lian Chen,Ping Wu,Kongwei Xie,Jianping Li,Bin Xu,Gaoping Cao,Yu Chen,Yawen Tang,Yiming Zhou,Tianhong Lu,Yusheng Yang.FePO 4 nanoparticles embedded in a large mesoporous carbon matrix as a high-capacity and high-rate cathode for lithium-ion batteries[J]. Electrochimica Acta . 2013
  • 3Jianping Li,Ping Wu,Feijian Lou,Peng Zhang,Yawen Tang,Yiming Zhou,Tianhong Lu.Mesoporous carbon anchored with SnS 2 nanosheets as an advanced anode for lithium-ion batteries[J]. Electrochimica Acta . 2013
  • 4Ping Wu,Ning Du,Jie Liu,Hui Zhang,Jingxue Yu,Deren Yang.Solvothermal synthesis of carbon-coated tin nanorods for superior reversible lithium ion storage[J]. Materials Research Bulletin . 2011 (12)
  • 5Bin Xu,Lu Shi,Xianwei Guo,Lu Peng,Zhaoxiang Wang,Shi Chen,Gaoping Cao,Feng Wu,Yusheng Yang.Nano-CaCO 3 templated mesoporous carbon as anode material for Li-ion batteries[J]. Electrochimica Acta . 2011 (18)
  • 6Bin Xu,Lu Peng,Guoqing Wang,Gaoping Cao,Feng Wu.Easy synthesis of mesoporous carbon using nano-CaCO 3 as template[J]. Carbon . 2010 (8)
  • 7G.Derrien,J.Hassoun,S.Panero,B.Scrosati.Nanostructured Sn–C Composite as an Advanced Anode Material in High‐Performance Lithium‐Ion Batteries[J]. Adv. Mater. . 2007 (17)
  • 8Zhang, Wei-Ming,Hu, Jin-Song,Guo, Yu-Guo,Zheng, Shu-Fa,Zhong, Liang-Shu,Song, Wei-Guo,Wan, Li-Jun.Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries. Advanced Materials . 2008
  • 9Laifa Shen,Xiaogang Zhang,Evan Uchaker.Li4Ti5O12 Nanoparticles Embedded in a Mesoporous Carbon Matrix as a Superior Anode Material for High Rate Lithium Ion Batteries. ADVANCED ENERGY MATERIALS . 2012
  • 10Jing Wang,Donglin Li,Xiaoyong Fan,Lei Gou,Jingjing Wang,Yan Li,Xiaoting Lu,Qian Li.Facile synthesis of Sn– C nanocomposite as an anode material for lithium ion batteries. Journal of Alloys and Compounds . 2012

同被引文献8

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部