摘要
用膨胀计法研究了 12 -磷钼酸的自由基阻聚反应动力学 .实验证明 ,在苯乙烯自由基聚合过程中 12 -磷钼酸确实抑制了聚合反应速率 .动力学数据表明 ,苯乙烯自由基聚合反应速率的改变值与 12 -磷钼酸浓度的 0 .16次幂成正比 .
Effect of 12phosphomolybdic acid on free radical polymerization was studied in this paper with a dilatometer. In the process of free radical polymerization of styrene, 12phosphomolybdic acid did play its role in restraining the polymerization rate. And the kinetic data showed that the changed polymerization rate was proportional to 0.16 exponential of the concentration of 12phosphomolybdic acid.
出处
《兰州大学学报(自然科学版)》
CAS
CSCD
北大核心
2002年第6期68-71,共4页
Journal of Lanzhou University(Natural Sciences)