摘要
A space design for the molecule of hydrocarbon based on the traditional group division method is developed, and a group vector space method (GVSM) for estimating critical property of hydrocarbon is proposed by using the module index of the group vector to characterize the group position in the molecule. Expressions for estimating critical properties T_c,p_c and V_c of hydrocarbons are proposed, with the numerical values of relative group parameters presented. The average percentage deviations of T_c,p_c and V_c estimation are 0.62, 2.3 and 1.6 respectively.
A space design for the molecule of hydrocarbon based on the traditional group division method is developed, and a group vector space method (GVSM) for estimating critical property of hydrocarbon is proposed by using the module index of the group vector to characterize the group position in the molecule. Expressions for estimating critical properties T_c,p_c and V_c of hydrocarbons are proposed, with the numerical values of relative group parameters presented. The average percentage deviations of T_c,p_c and V_c estimation are 0.62, 2.3 and 1.6 respectively.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2003年第1期112-114,共3页
CIESC Journal
关键词
估算
烃类物质
基团向量空间方法
临界性质
hydrocarbons, group vector space method, critical property,estimation of physical property
