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多尺度作用的D_4/APAEDMS本体共聚过程仿真 被引量：3

MULTIDIMENSION BULK-COPOLYMERIZATION MODEL OF OCTAMETHYLCYCLOTETRASILOXANE AND AMINO-SILICONE MONOMER
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摘要 For high viscosity bulk-copolymerization of octamethylcyclotetrasiloxane and amino-silicone monomer, a multisyphon flow physical model was established.Based on the free volume and chemical reaction kinetic theories, a new computational model was developed to simulate the multisyphon flow model. As to the new model, the united influence of reaction and diffusion was reviewed and analyzed. The new model was used to simulate bulk- copolymerization of octamethylcyclotetrasiloxane and amino-silicone monomer and agreed well with the results. For high viscosity bulk-copolymerization of octamethylcyclotetrasiloxane and amino-silicone monomer, a multisyphon flow physical model was established.Based on the free volume and chemical reaction kinetic theories, a new computational model was developed to simulate the multisyphon flow model. As to the new model, the united influence of reaction and diffusion was reviewed and analyzed. The new model was used to simulate bulk- copolymerization of octamethylcyclotetrasiloxane and amino-silicone monomer and agreed well with the results.
作者 罗正鸿 詹晓力 陈丰秋 阳永荣
机构地区 浙江大学化学工程与生物工程学系
出处 《化工学报》 EI CAS CSCD 北大核心 2003年第1期131-134,共4页 CIESC Journal
关键词 多尺度作用 D4/APAEDMS 本体共聚 过程仿真 氨取代基有机硅单体 八甲基环四硅氧烷 反应-扩散联合动力学 amino-silicone monomer,octamethylcyclotetrasiloxane,multisyphon flow model,reaction-diffusion united kinetics
分类号 O634.41 [理学—高分子化学] O631.5 [理学—高分子化学]
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参考文献8

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  • 3[3]Luo Zhenghong(罗正鸿), Zhan Xiaoli(詹晓力), Chen Fengqiu(陈丰秋), Yang Yongrong(阳永荣),et al.Copolymerization Kinetics of Octamethylcyclotetrasiloxane and Amino-silicone Monomer.Chemical Reaction Eengineering and Technology (化学反应工程与工艺), 2002,18(1):58-65
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同被引文献20

  • 1罗正鸿,詹晓力,陈丰秋,阳永荣.D_4/APAEDMS本体开环共聚反应的Monte Carlo模拟[J].化工学报,2004,55(6):991-997. 被引量：1
  • 2Harrison A J, Eyre J A. The effect of obstacle arrays on the combustion of large premixed gas/air clouds. Combust and Tech , 1987, 52:121-137.
  • 3Masri A R, Ibrahim S S, Nehzat N, Green A R. Experimental study of premixed flame propagation over various solid obstructions. Experimental Thermal and Fluid Science, 2000, 21:109-116.
  • 4Popat N R, Catlin C A, Amtzen B J. Investigation to improve and assess the accuracy of computational fluid dynamics based explosion models. Journal of Hazardous Materials, 1996, 44:1- 25.
  • 5Grubb W T, Robert C O. Kinetics of the Polymerization of a cyclic dimethylsiloxane. J. Polymer Science : Part C, 1955,55 (6):1408-1411.
  • 6Cazacu M, Marcu M, Vlad A. Synthesis of functional telechelid polydimethylsiloxanes by ion-exchangers catalysis.European Polymer Journal, 1999, 35:1629-1635.
  • 7罗正鸿.[D].Hangzhou:浙江大学,2003.
  • 8Grubb W T;Robert C O.查看详情,1955(06).
  • 9Cazacu M;Marcu M;Vlad A.Synthesis of functional telechelic polydimethylsiloxanes by ion-exchangers catalysis[J],1999(9).
  • 10Gillespie D T.查看详情[J],1977(25).

引证文献3

二级引证文献8

化工学报
2003年 第1期

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