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后重氮偶合法制备咔唑类光折变聚合物 被引量:4

Preparation of Carbazole-based PhotorefractivePolymer via Post-Azo-Coupling Reaction
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摘要 A new kind of carbazole-based photorefractive polymer was prepared via a post-azo- coupling reaction. The structure of the polymer was characterized by IR, 1H NMR, UV-vis and GPC. The IR and UV-vis spectra demonstrated that azo group was grafted to the polymer in content of 15.56%. The molecular weight of the polymer as determined by GPC was higher than that of the polymer obtained by common method. A new kind of carbazole-based photorefractive polymer was prepared via a post-azo- coupling reaction. The structure of the polymer was characterized by IR, 1H NMR, UV-vis and GPC. The IR and UV-vis spectra demonstrated that azo group was grafted to the polymer in content of 15.56%. The molecular weight of the polymer as determined by GPC was higher than that of the polymer obtained by common method.
出处 《应用化学》 CAS CSCD 北大核心 2003年第2期189-191,共3页 Chinese Journal of Applied Chemistry
基金 河南省杰出青年基金资助 ( 1999年 )
关键词 后重氮偶合法 制备 咔唑 光折变聚合物 生色团 光折变机理 carbazole,photorefractive polymer,post azo coupling reaction,chromophore
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参考文献4

  • 1[1]Gunter P,Huignard J P. Photorefractive Materials and Their Applications[M]. New York:Spinger,1988:1
  • 2[2]Yu F,Yin S. Photorefractive Optics:Materials, Properties and Applications[M]. San Diego:Academic,2000:3
  • 3[3]Ho M S,Barrett C,Paterson J, et al. Macromolecules[J],1996,29:4 613
  • 4[4]Ito S,Ohmori S,Yamamoto M. Macromolecules[J],1992,25:185

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