摘要
The synthesis of tri(β-chloroethyl)phosphate(TCEP) from ethylene oxide and phosphorus oxychloride catalyzed by a solid super acid TiSiW 12O 40/TiO 2 has been studied. The optimun reactions conditions are: molar ratio of ethylene oxide to phosphorous oxychloride=3.10∶1.00, catalyst amount 1.5%, 5 h and 30～45 ℃.
The synthesis of tri(β-chloroethyl)phosphate(TCEP) from ethylene oxide and phosphorus oxychloride catalyzed by a solid super acid TiSiW 12O 40/TiO 2 has been studied. The optimun reactions conditions are: molar ratio of ethylene oxide to phosphorous oxychloride=3.10∶1.00, catalyst amount 1.5%, 5 h and 30～45 ℃.
出处
《应用化学》
CAS
CSCD
北大核心
2003年第2期201-202,共2页
Chinese Journal of Applied Chemistry
