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芳茂铁四氟硼酸盐的制备 被引量：3

Preparation of cationic photoinitiator [Cp-Fe-arene]BF_4
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摘要 以二茂铁为原料制备了多种阳离子光引发剂芳茂铁四氟硼酸盐 ,其中包括两种新物质 ,即两种带乙酰基的芳茂铁四氟硼酸盐 ,分别为 [环戊二烯基 铁 ( 2 ,5 二甲基苯乙酮 ) ]四氟硼酸盐和 [(乙酰基 环戊二烯基 ) 铁 对二甲苯 ]四氟硼酸盐。另外 ,本文考察了此配体交换反应的反应条件对反应收率的影响 。 Several arene-cyclopentadienyl iron tetroflouroborate salts with different structures were synthesized with ferrocene, including two complexes with acetyl group. They are [cyclopentadienyl -Fe-2,5-dimethyl-hypnone]BF_4 and [acetyl-cyclopentadienyl -Fe-p-xylene]BF_4. In addition, the conditions reaction of the ligand exchange and product purification were also be studied.
作者 王涛 杜洪光 黄毓礼
机构地区 北京化工大学理学院 北京化工大学材料科学与工程学院
出处 《北京化工大学学报（自然科学版）》 CAS CSCD 2003年第1期83-85,91,共4页 Journal of Beijing University of Chemical Technology(Natural Science Edition)
基金 国家自然科学基金 ( 2 97760 0 2 )
关键词 制备 二茂铁 芳茂铁 四氟硼酸盐 配体交换反应 阳离子光引发剂 ferrocene arene-cyclopentadienyl iron tetroflouroborate ligand exchange reaction
分类号 O627.81 [理学—有机化学]
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参考文献6

  • 1[1]Lohse F, Zweifel H. Recent advances in cationic photopolymerization of epoxides[J]. Adv in polym Sci, 1986,78:69-76
  • 2[2]Hans Z, Kurt M. Imaging with cationic organometallic photoinitiators[J]. Am Chem Soc: Div Polym Chem,1985,26(2):347-348
  • 3[3]Timmons. Cyclopentadienyliron complex salt, process for preparing the same and photopolymerizable composition containing the same[P]. USP 5354784. 1994-10-11
  • 4[4]William H, Morrison, Ellen Y, et al. Reaction of ferrocene with polyaromatic molecules[J]. J Am Chem Soc, 1974,29:237-242
  • 5[5]Graham P J, Lindsey R V. Some acyl ferrocenes and their reactions[J]. J Am Chem Soc, 1957,79:3416-3419
  • 6[6]Astruc D, Dabard R. Organo-iron complexes of aromatic compounds[J]. Tetrahedron, 1983,39(24):4027-4095

同被引文献20

  • 1陈旭东,黄新华,陈用烈,梁兆熙.铁－芳烃络合物光引发剂的吸收光谱研究[J].高等学校化学学报,1994,15(4):627-629. 被引量：3
  • 2陈旭东,李康业,陈用烈.环戊二烯异丙苯铁六氟磷酸盐的光解反应研究[J].科学通报,1995,40(3):284-285. 被引量：3
  • 3Richard A Brown, Andrew Houlton, Steven D Howe, Roger M G Roberts, Jack Silver. Studies of the bonding in iron (Ⅱ) cyclopentadienyl and arene sandwich compounds part 4 A survey of the effect of methyl substitution on the bonding in same iron sandwich com
  • 4Crivello J V, Lam J H W. Dye-sensitized photoinitiated cationic polymerization[J]. J. Polymn. Sci., Part A, 1978,16,2441-2451.
  • 5Hans Z, Kurt M. Imaging with cationic organometallic photoinitiators [J]. Am. Chem. Soc. Div. Polym. Chem.,1985,26 (2): 347-348.
  • 6Timmons. Cyclopentadienyl iron complex salt, process for preparing the same and photopolymerizable composition containing the same[P]. US Patent ,5 354 784.
  • 7Vincent Desobry, Marly, Hans O Doggweiler, Mohlin. Process for the preparation of organometallic compounds[P].US Patent ,4 992 572.
  • 8Fouassier J P, AUonas X, Burget D. Photopolymerization reactions under visible lights: principle, mechanisms and examples of applications [ J ]. Progress in Organic Coatings, 2003,47:16-23.
  • 9Crivello J V. The discovery and development of onium salt eationie photoinitiator [J ]. J Polym Sei: Part A:Polymer Chemistry, 1999, 37:4241 - 4254.
  • 10Crivello J V, Sangermano M. Visible and long-wavelength photoinitiated cationic polymerization[J]. J Polym Sci: Part A: Polymer Chemistry, 2001,39 : 343 - 348.

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北京化工大学学报（自然科学版）
2003年 第1期

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