1,1′-联萘-2,2′-二胺的合成及在不对称合成中的应用

Preparation and Application in Asymmetrical Synthesis of 2,2′-Diamino-1,1′-binaphthalene

综述了 1,1′ 联萘 2 ,2′ 二胺 (联萘胺 )化合物的制备 ,讨论了它们作为手性辅助基或配体在烯烃、酮、亚胺的不对称氢化及在烯烃的不对称环丙烷化、醛的烷基化反应、醛的不对称烯丙基化反应、不对称烯丙位取代反应和不对称Diels Alder反应等反应中的应用 .

This paper presents a brief review of preparation of 2, 2'-diamino-1, 1-binaphthalene compounds and outlines the progress in their application as a chiral auxiliary or a ligand in the asymmetric hydrogenation of alkenes, ketones and imines, and in the asymmetric cyclopanation of olefins, alkylation and allylation of aldehydes, allylic substitution and enantioselective Diels-Alder reaction.