摘要
N,N’-bis(salicylidene)ethylenediamin complexes with rare earth ions,Nd(Ⅲ),Gd(Ⅲ) and Yb(Ⅲ),were synthesized and characterized with elemental analysis,UV-Vis spectroscopy,infrared spectroscopy and TG-DTG analysis.The Schiff base ligand forms 1∶1 complex with Nd(Ⅲ)ion,but 2∶3 complexes with Gd(Ⅲ) or Yb(Ⅲ)ion.When excited with blue laser,Nd(Ⅲ) and Yb(Ⅲ) complexes give strong near-infrared fluorescence,which shows potential application in fluoroimmunoassay.
N,N'-bis(salicylidene)ethylenediamin complexes with rare earth ions,Nd(Ⅲ),Gd(Ⅲ) and Yb(Ⅲ),were synthesized and characterized with elemental analysis,UV-Vis spectroscopy,infrared spectroscopy and TG-DTG analysis.The Schiff base ligand forms 1∶1 complex with Nd(Ⅲ)ion,but 2∶3 complexes with Gd(Ⅲ) or Yb(Ⅲ)ion.When excited with blue laser,Nd(Ⅲ) and Yb(Ⅲ) complexes give strong near-infrared fluorescence,which shows potential application in fluoroimmunoassay.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2003年第1期99-100,共2页
Chemical Research and Application
基金
广东省自然科学基金资助项目
关键词
Shiff碱
稀土
近红外发光
schiff base
rare earth
near-infrared fluorescence
