2,7,12,17-四(甲硫基)-3,8,13,18-四(苯甲酰硫基)四氮杂卟啉及其Mg(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ)配合物的合成与表征

Synthesis and Characterization of 2,7,12,17-Tetra(methylthio)-3,8, 13,18-Tetra(benzoyIthio)tetraazaporphyrin and Its Coordination Compounds with Mg( Ⅱ ), Cu( Ⅱ ) and Ni( Ⅱ )

硫杂酞菁、含硫取代基的四氮杂卟啉及其金属配合物由于具有优异的光、电及催化性能而日益受到重视.据此,我们以自制的1-甲硫基-2-苯甲酰硫基马来二腈(MBM)为原料,合成了2,7,12,17-四(甲硫基)-3,8,13,18-四(苯甲酸硫基)四氮杂卟啉H_2T(mbm)TAP及其Mg(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ)配合物MT(mbm)TAP,经IR、UV-Vis和DTA等进行了表征.

The title compounds, 2, 7,12,17-Tetra(methylthio)-3,8,13,18-tetra(benzoylthio) tetraazaporphyrin [H2T(mbm)TAP] and its metal complexes[MT(mbm)TAP, M = Mg( Ⅱ ), Cu ( Ⅱ ), Ni ( Ⅱ )], were synthesized from l-methylthio-2-benzoylthiomaleonitrile. The new compounds were characterized by elemental analysis, IR, UV-Vis spectra and DTA.