邻苯二甲酸异丙酯酰氧基-丙烯酰氧基-乙酰乙酸乙酯络铝及其聚合物的合成与荧光性质

Studies on Synthesis and Fluorescent Property of Aluminium Isopropyl Phthalate Acryloxyl Ethyl acetoacetate and Its Polymer

通过异丙氧基铝和邻苯二甲酸酐、乙酰乙酸乙酯及丙烯酸反应,合成了螯合物单体邻苯二甲酸异丙酯酰氧基-丙烯酰氧基-乙酰乙酸乙酯络铝,由自由基聚合法合成了聚合物,用元素分析仪、VPO、IR、~1H NMR和^(27)Al NMR证实了它们的结构,并研究了它们在DMF中的荧光性质。

Chelate compound aluminium isopropyl phthalate acryloxyl ethylacetoacetate (AIPAE) has been synthesized by the reaction of aluminium triisopropoxide with phthalic anhydride, ethylacetoacetate and acrylic acid. Chelate polymer PAIPAE has been synthesized by radical polymerization of AIPAE. The structures of AIPAE and PAIPAE have been determinated by elemental analyzer, ICP, IR, 1H NMR and 27Al NMR. Their fluorescent property in DMF has mainly been studied.