可逆反应的热动力学研究——数学模型和研究法

Studies on Thermokinetics of Reversible Reaction Kinetics——Mathematical Models and Studying Methods

本文根据热动力学的理论和方法,建立了二种可逆反应动力学的数学模型和研究方法,并通过氨与硝基乙烷的2—2型和准1—1型可逆反应的热动力学加以验证。

Based on the theory and method of thermokinetics proposed in previous articles, two kinds of mathematical models and studying methods for the reversible reaction kinetics are suggested in this paper. The thermokinetics for the reversible reaction between ammonia and ni-troethane has been studied at 25 and 30℃ by using the two kinds of models and methods. The results indicate that the two kinds of mathematical models and studying methods for the reversible reaction kinetics are believed to be correct.