IPBAA及其聚合物的热稳定性和荧光性质研究

STUDIES ON HEAT-STABILITY AND FLUORESCENT OF IPBAA AND ITS POLYMER

以异丙基铝与邻苯二甲酸酐、苯甲酸和丙烯酸反应,合成了螯合物邻苯二甲酸异丙酯酰氧基-苯甲酰氧基-丙烯酰氧基铝(IPBAA);以IPBAA为单体合成了聚合物PIPBAA。对它们的结构进行了表征,并研究了PIPBAA的热稳定性及IPBAA和PIPBAA在DMF中的荧光性质。

Chelate compound Isopropyl phthalate-oyloxyl-benzyloyloxyl-acryloyloxyl aluminium (IP-BAA )has been synthesized by the reaction of aluminium triisopropoxide with phthalic anhydride, benzole acid and acrylic acid. Chelate polymer PIPBAA has been synthesized by radical polymerization of IPBAA. Their structures have been determinated. Heat-stability and fluorescent property of IPBAA and PIPBAA in DMF have been studied.