自由基聚合动力学常数关系新图解

A New Diagram Relating Kinetic Parameters of Free-Radical Polymerization

在自由基聚合速率常数(k_p、k_t、k_d)与可测参数(R_p、X_??、τ、〔M〕)间的关系提出新图解,以加深学习时的理解.

In the past decade the lower concentration of free radical in the polymerization systems may be measured precisely by ESR and other methods.Thus, a new diagram relating four measurable variables (P_p, X_n,τ,〔M〕) and kinetic parameters (k_p, k_t, k_a) is extended and developed from Hiemenz′s three-parameter diagram.