摘要
利用公式ΔH =- 0 .1196n/λ计算了甲醇和乙醇燃烧反应的理论火焰温度 ,提出了醇燃烧反应的机理 .该机理为 :(1)O2 +ν→ 2O· ;(2 )CmH2m + 1OH→CmH2m +H2 O ;(3)CmH2m →mC +mH2 ;(4 )H2 +O·→H2 O +hν ;(5 )C +O·→CO +hν;(6 ) 2CO +O2 → 2CO2 .
The flame temperatures produced by burning of CH 3OH and CH 3CH 2OH were calculated, with the mechanism of alcohol combustion reaction being deduced as follows: (1) O 2+hν→2O·;(2) C mH 2m+1 OH→C mH 2m +H 2O;(3) C mH 2m →mC+mH 2;(4)H 2+O·→H 2O+hν; (5) C+O·→CO+hν; (6) 2CO+O 2→2CO 2.
出处
《辽宁大学学报（自然科学版）》
CAS
2003年第1期63-66,共4页
Journal of Liaoning University：Natural Sciences Edition
