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过渡金属化合物对P(SBR/N330)硫化胶的增强作用 被引量:3

Reinforcing Effect of Transition-metal Compounds on P(SBR/N330) Vulcanized Rubber
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摘要 用过渡金属及稀土化合物对高耐磨炭黑(N330)进行表面改性,探讨提高高耐磨炭黑填充型粉末丁苯橡胶(SBR)硫化胶的力学性能.结果表明,用Co(OH)3/NH4OH及铈化合物对N330进行表面改性后,能显著提高其硫化胶的300%定伸应力.拉伸断面形貌的SEM分析表明,N330经Co(OH)3/NH4OH及铈化合物改性后,其在SBR基体中的分散良好,界面粘合牢固. The surface of high anti-abrasion carbon black(N330) was modified by some transition-metals or rare earth compounds, effect on the mechanical properties of N330 filled SBR powder vulcanized rubber was investigated. The results showed that after N330 was modified by Co(OH)3/NH4OH and cerium compounds, 300% stretching stress of the vulcanized rubber was increased notable. The surface morphology of tensile fracture analyzed by SEM showed that after N330 modified by Co(OH)3/NH4OH and cerium compounds, it was dispersed uniformly in SBR matrix and the interfaces adhered very tightly.
出处 《华南理工大学学报(自然科学版)》 EI CAS CSCD 北大核心 2003年第2期91-95,共5页 Journal of South China University of Technology(Natural Science Edition)
基金 国家自然科学基金资助项目(59773010)
关键词 过渡金属化合物 硫化胶 增强作用 粉末丁苯橡胶 炭黑 表面改性 力学性能 拉伸断面形貌 SBR powder transition-metal surface modification of carbon black mechanical property morphology of tensile fracture
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