水介质中可控活性自由基聚合的研究进展

The Development of Controlled/living Radical Polymerization in Aqueous Media

综述了均相水溶液体系和分散、悬浮、乳液及微乳液等非均相水溶液体系中的可控 活性自由基聚合的研究现状。对一些最常见的可控自由基聚合方法 ,如氮氧调控聚合、原子转移自由基聚合和可逆加成 断裂链转移聚合方法的聚合情况进行了详细的介绍。展望了水介质中可控

Controlled/living radical polymerizations carried out in the presence of water have been examined.These aqueous systems include both the homogeneous and the various heterogeneous,namely dispersion,suspension,emulsion and miniemulsion,Among them,the most common methods allowing control of the radical polymerization,such as nitroxide-mediated polymerization,atom transfer radical polymerization and reversible addition-fragmentation transfer,are presented in detail.Good prospects for controlled/living radical polymerization in aqueous media are also shown.