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原位固体核磁共振研究温和条件下丙烷在镓改性H-ZSM-5上的活化 被引量:4

In situ MAS NMR Study on Propane Activation over Ga-modified H-ZSM-5 Under Mild Condition
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摘要 C MAS NMR has been performed in situ to investigate the activation of 13C labeled propane under a mild condition over Ga-modified H-ZSM-5 catalysts prepared via different methods. The results indicate that the ion-exchanged and/or its related Ga species are the highly active catalytic components, while impregnated Ga species is not the active species for propane activation at 573 K. C MAS NMR has been performed in situ to investigate the activation of 13C labeled propane under a mild condition over Ga-modified H-ZSM-5 catalysts prepared via different methods. The results indicate that the ion-exchanged and/or its related Ga species are the highly active catalytic components, while impregnated Ga species is not the active species for propane activation at 573 K.
机构地区 复旦大学化学系
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2003年第3期525-527,共3页 Chemical Journal of Chinese Universities
基金 教育部科学技术重点项目 国家杰出青年基金 (批准号 :2 0 0 0 5 310 )资助
关键词 原位固体核磁共振 丙烷 改性 H-ZSM-5 分子筛催化剂 烷烃 芳构化 活化 In situ MAS NMR Propane Activation Mild condition H-ZSM-5
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  • 1刘红梅 李涛 徐奕德.Chem. J. Chinese Universities(高等学校化学学报)[J],2002,23(8):1-1.

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