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间接光度法测定饮水中二氧化氯与氯的浓度 被引量:2

The Indirect Spectrophototometric Determination of Chlorine Dioxide and Chlorine in the Drinking Water
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摘要 In acidic medium, malonic used as masking agent, let the mixed aqueous of chlorine dioxide and chlorine react with Fe2+, then have the residual Fe2+ coloured with 1.10phenanthroline solution. The authors can quantify the content of chlorine dioxide and chlorine in the water by detecting the difference of absorbtivity of the coloured solution when it is no masking agent and it is added masking agent. The method is simple, innocuity, specific, quick, accurate and sensitive. The mini detect limitation are:Chlorine: 7.66×10-3mg/L,dioxide Chlorine: 2.91×10-3mg/L.R is 0.9997,CV is 2.55%. In acidic medium, malonic used as masking agent, let the mixed aqueous of chlorine dioxide and chlorine react with Fe2+, then have the residual Fe2+ coloured with 1.10phenanthroline solution. The authors can quantify the content of chlorine dioxide and chlorine in the water by detecting the difference of absorbtivity of the coloured solution when it is no masking agent and it is added masking agent. The method is simple, innocuity, specific, quick, accurate and sensitive. The mini detect limitation are:Chlorine: 7.66×10-3mg/L,dioxide Chlorine: 2.91×10-3mg/L.R is 0.9997,CV is 2.55%.
出处 《四川大学学报(自然科学版)》 CAS CSCD 北大核心 2003年第1期174-177,共4页 Journal of Sichuan University(Natural Science Edition)
关键词 间接光度法 饮水检测 浓度测定 氯气 残余量 indirect spectrophotometry chlorine dioxide chlorine concentration determination Fe^(2+).
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参考文献2

  • 1武汉大学主编.分析化学试验(第三版)[M].北京:高等教育出版社,1994.155-157.
  • 2宋仁元 张亚杰 王维一 等译.水和废水标准检验法(第十五版)[M].北京:中国建筑工业出版社出版,1985.259-265.

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