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ESTIMATION OF ACTIVATED ENERGY OF DESORPTION OF n-HEXANE ON ACTIVATED CARBONS BY TPD TECHNIQUE 被引量:2

ESTIMATION OF ACTIVATED ENERGY OF DESORPTION OF n-HEXANE ON ACTIVATED CARBONS BY TPD TECHNIQUE
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摘要 In this paper, six kinds of activated carbons such as Ag+-activated carbon, Cu2+- activated carbon, Fe3+- activated carbon, activated carbon, Ba2+- activated carbon and Ca2+- activated carbon were prepared. The model for estimating activated energy of desorption was established. Temperature-programmed desorption (TPD) experiments were conducted to measure the TPD curves of n-hexanol and then estimate the activation energy for desorption of n-hexanol on the activated carbons. Results showed that the activation energy for the desorption of n-hexanol on the Ag+- activated carbon, the Cu2+- activated carbon and the Fe3+- activated carbon were higher than those of n-hexanol on the activated carbon, the Ca2+- activated carbon and the Ba2+- activated carbon. In this paper, six kinds of activated carbons such as Ag+-activated carbon, Cu2+- activated carbon, Fe3+- activated carbon, activated carbon, Ba2+- activated carbon and Ca2+- activated carbon were prepared. The model for estimating activated energy of desorption was established. Temperature-programmed desorption (TPD) experiments were conducted to measure the TPD curves of n-hexanol and then estimate the activation energy for desorption of n-hexanol on the activated carbons. Results showed that the activation energy for the desorption of n-hexanol on the Ag+- activated carbon, the Cu2+- activated carbon and the Fe3+- activated carbon were higher than those of n-hexanol on the activated carbon, the Ca2+- activated carbon and the Ba2+- activated carbon.
出处 《Chinese Journal of Reactive Polymers》 2001年第2期113-120,共8页 中国反应性高分子(英文版)
基金 The National Natural Scientific Foundation of China. (Project grant No. 29936100)
关键词 TPD VOCs N-HEXANOL Desorption activated energy. 有机化合物 解吸 n-乙烷
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