摘要
卤素-卤素(X···X)相互作用是一类强的分子间相互作用,这种非共价键分子间的相互作用对有机π分子的聚集态结构和光电特性具有重要的影响.本文通过在反式二苯乙烯类化合物骨架上引入给电子基团甲硫基和调节卤素取代基的位置,实现了分子间卤素-卤素相互作用的可控构筑,并进一步研究了卤素-卤素相互作用对卤代反式二苯乙烯类分子聚集态和发光特性的影响.该实验结果为调控有机π分子聚集态结构,获得高性能有机光电材料提供了新思路.
Halogen-halogen(X···X) interaction is a kind of strong intermolecular interaction. This interaction has great impact on the aggregation structures and optoelectronic properties of organic π-conjugated molecules. However, it is still a great challenge to tune the X···X interactions among organic π-conjugated molecules. In this article, with transstilbene as an example, the regulation of halogen-halogen interactions between organic π-conjugated molecules is achieved through chemical structure modification, that is introducing electron-donating methylthio group and changing the position of halogen substituents on trans-stilbene skeleton. The influence of halogen-halogen interactions on the aggregation structure and luminescence properties of trans-stilbenes was investigated.
作者
魏启兵
吴洪卓
乔小兰
赵宝国
李洪祥
Qibing Wei;Hongzhuo Wu;Xiaolan Qiao;Baoguo Zhao;Hongxiang Li(Key Laboratory of Resource Science,Ministry of Education,Shanghai Normal University,Shanghai Key Laboratory of Rare Earth Functional Materials,Shanghai 200234,China;Key Laboratory of Organic Functional Molecular Synthesis and Assembly Chemistry,Chinese Academy of Sciences,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China)
出处
《中国科学:化学》
CAS
CSCD
北大核心
2019年第2期338-345,共8页
SCIENTIA SINICA Chimica
基金
国家自然科学基金(编号:21672252
21472116)
上海启明星计划(编号:18QA1405000)
中国科学院青年创新促进会(编号:2018290)资助项目