摘要
自由基阴离子配体是一种具有特殊电子结构的配体,与其它配合物相比,含有自由基的配合物在有机磁性材料和过渡金属催化反应中体现了其独有的性质和应用可能性。自由基阴离子根据其结构可划分为5种类型,即亚胺半醌自由基、亚胺醌自由基,氮氧自由基,杂环自由基以及其它类型自由基。介绍了这些自由基的结构特点和其配合物的性能,并对其最新研究进展进行了综述。
The radical anion ligands is a kind of ligands with special electronic structure,and as compared with other complexes containing radical complexes in organic magnetic material and transition metal catalyzed reaction can reflect its unique properties and application possibility.Free radical anion can be divided into five types according to their structure,namely,the free radical of the polyimide,the free radical of the radical,the oxygen free radical,and the heterocyclic radical.This paper introduced the structural features of these free radicals,and the properties of their complexes,and the latest research progress were also reviewed.
出处
《化工科技》
CAS
2016年第2期57-63,共7页
Science & Technology in Chemical Industry
基金
国家自然科学基金项目(20972025
U1362110)
黑龙江省留学归国人员科学基金项目(41417837-8-08016)
黑龙江省教育厅海外学人科研资助项目(1154H14)
