交联长链高分子交联结构的表征与评价

ON THE CHARACTERIZATION EVALUATION FOR CROSS-LINK STRUCTURE OF THE CROSS-LINKED LONG-CHAIN POLYMERS

本文详细地讨论了分子内交联对交联长链高分子凝胶点以后诸平均物理性质的影响。从概率论的基本定律出发,得到了溶胶分数、溶胶平均分子量与交联度的定量关系式。

In this paper we discuss in detail the effect of intramolecular crosslinking on the post-gelation average physical properties. The quantitative relatioas for the Sol fraction, the average molecular weight in the sol, and the cross-link density are obtained by using the elemetary laws of probabilify theory.