摘要
综述了β-K_3H_3[SiW_(11)Mn(H_2O)O_(39)]·13H_2O、[Fe(C_5H_5)_2]_3K_3[SiMo_(11)O_(39)M(H_2O)]、纳米H_3PW_12O_(40)/SiO_2·9H_2O复合型杂多酸、H_3PW_(12)O_(40)/ZrO_2-WO_3、硅烷化改性凹凸棒石负载磷钨钼杂多酸、TiSiW_(12)O_(14)/TiO_2,固体超强酸S_2O_8^(2-)/ZrO_2、SO_4^(2-)/TiO_2-Al_2O_3、AlCl_3·CuSO_4,无机化合物硫酸铈铵、硫酸钛、氧化亚锡、磺化硅胶、含磺酸基的介孔分子筛d-SBA-15-SO_3H、非晶态氧化亚锡基硼磷铝酸盐以及有机酸PTSA、对甲苯磺酸催化剂催化合成乙酸正戊酯的实验结果。
The catalytic synthesis of amyl acetate with β-K_3H_3[SiW_(11)Mn(H_2O)O_(39)]·13H_2O, [Fe(C_5H_5)_2]_3K_3[SiMo_(11)O_(39)M(H_2O)], H_3PW_(12)O_(40)/SiO_2·9H_2O, H_3PW_(12)O_(40)/ZrO_2-WO_3, silylated-attapulgite supported 12-heteropolyacid of Molybdenum and Tungsten catalyst,TiSiW_(12)O_(14)/TiO_2, solid superacid S_2O_8^(2-)/ZrO_2,SO_4^(2-)/TiO_2-Al_2O_3, AlCl_3·CuSO_4, ammonium ceric sulfate, titanium sulfate, SnO, sulfonated silicone, SBA-15 mesoporous zeolite functionalized with sulfonic acid group, TAPB, PTSA as catalyst were introduced. The results showed that heteropoly acid catalyst performance is relatively better.
出处
《乙醛醋酸化工》
2016年第3期12-14,24+8,共5页
Acetaldehyde Acetic Acid Chemical Industry
关键词
乙酸正戊酯
催化剂
酯化反应
Amyl acetate
catalyst
esterification reaction
