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THE SOLVENT EFFECTS ON THE RATE OF THE REACTION OF 2.4-DINITROFLUOROBENZENE WITH THE ETHYL ESTER OF TYROSINE

THE SOLVENT EFFECTS ON THE RATE OF THE REACTION OF 2.4-DINITROFLUOROBENZENE WITH THE ETHYL ESTER OF TYROSINE
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摘要 Although the dielectric constant (ε) and the permanent dipole moment (μ) of solvents have for a long time been used to describe the polarity of solvents, but they can only describe the nonspecific clectrostatic interactions. In addition, between solute and solvent molecules there are also some specific interactions such as electron pair donor and accepter (EPD/EPA), hydrogen bond donor and accepter (HBD/HBA), etc. In recent years, by means of spectroscopic measurements and other methods, many empirical solvents parameters have been established, such as the Lewis acidity parameter Er(30), donor
作者 朱重远
机构地区 Chemistry Department
出处 《Chinese Science Bulletin》 SCIE EI CAS 1984年第4期567-568,共2页
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