摘要
本文研究了[Fe_3(μ_3-O)(μ-O_2CH)_6(H_2O)_2(O_2CH)]·2H_2O(简称<Fe_3F>)在乙炔、水汽体系中的反应行为。发现当温度高于220℃,脱落部分配体的<Fe_3F>具有活化乙炔进行加成反应的性能。采用原位红外光谱法和气相色谱法对此反应过程进行了跟踪探索,报道了产物的定性及半定量结果。
The reaction behavior of the title complex has been investigated in the system of acetylene with water vapor by in situ IR. and GC analysis. It has been observed that over 220℃ some components obtained by losing part of the ligands of the complex showed up activity for the addition reactions of acetylene forming the acetaldehyde, ethylene, acetone and butane. The results of the qualitative and semi-quantitative analysis were reported as well.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
1992年第3期25-28,42,共5页
Spectroscopy and Spectral Analysis
基金
福建省自然科学基金
福州结构化学开放实验室科学基金~~
关键词
反应行为
热解
铁簇合物
红外光谱
Reaction behavior, Thermal decomposition,Iron cluster,In situ infrared spectroscopy
