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化学发光分析法测定锰(Ⅱ)与锰(Ⅶ) 被引量:2

DETERMINATION OF Mn(Ⅱ) AND Mn(Ⅶ) BY CHEMILUMINESCENCE ANALYSIS
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摘要 基于MnO_4^-对碱性鲁米诺溶液的氧化发光作用,建立了测定Mn^(2+)和MnO_4^-的化学发光法。方法具有较高的灵敏度,线性范围达3个数量级,且选择性好,操作程序简便。已将该法应用于实际水样中锰(Ⅱ)和锰(Ⅶ)的测定,结果满意。 A chemiluminescence analysis of Mn(Ⅱ) and Mn(Ⅶ) has been devloped on the reaction of MnO_4^- with lominol. The method is sensitive, selective and convenient, and its linear dynamic range is over three orders. The proposed procedure has been satisfactorily applied to the determination of traces of Mn^(2+) and MnO_4^- in waste water samples.
出处 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 1992年第5期121-122,127,共3页 Spectroscopy and Spectral Analysis
关键词 乙醇 化学发光 氧化反应 Alcohol Chemiluminescence Oxidation reaction
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参考文献2

  • 1陆明刚,Talanta,1990年,37卷,4期,393页
  • 2吕小虎,环境科学与技术,1990年,2期,30页

同被引文献37

  • 1卢建忠,章竹君.化学发光消耗型锰传感器[J].高等学校化学学报,1995,16(7):1034-1036. 被引量:7
  • 2张海松,杨秀岑,伍莉萍.镀铜锌粒还原-流动注射-化学发光同时测定两种价态的铁[J].分析化学,1996,24(2):220-223. 被引量:10
  • 3林守麟,刘永庆.没食子酸-过氧化氢-甲醛体系中Co(Ⅱ)和Mn(Ⅱ)的化学发光同时测定[J].高等学校化学学报,1990,11(11):1199-1202. 被引量:7
  • 4Kei Okamura,Toshitaka Gamo,Hajime Obata,et al.Selective and Sensitive Determination of Trance Manganese in Sea Water by Flow Through Technique Using Luminol-Hydrogen Peroxide Chemiluminescence Detection[J].Anal Chim Acta.1998,377:125-131.
  • 5Abaji Gaikwad,Manuel Silva,Dolores Pérez-Bendito.Selective Stopped-Flow Determination of Manganese with Luminol in the Absence of Hydrogen Peroxide[J].Anal Chim Acta.1995,302:275-282.
  • 6Andrew R Bowie,Peter R Fielden,Roger D lowe, etal.Sensitive Determination of Manganeses Using Flow Injection and Chemiluminescent Detection[J].Analyst.1995,120(8):2119-2127.
  • 7Thomas P Chapin, Kenneth S Johnson, Kenneth H Coale. Rapid Determination of Manganese in Sea Water by Flow-Injection Analysis with Chemiluminescence Detection[J].Anal Chim Acta.1991,249:469-478.
  • 8Zhang Fan,Lin Qing-xiong. A New Chemiluminescence System: MnO-4-Na2CO3-KOH and Its Application in the Determination of Manganese[J]. Talanta. 1993,40(10):1557-1561.
  • 9Revin Robards,Paul J Worsfold.Analytical Applications of Liquid-Phase Chemiluminescence[J].Anal Chim Acta.1992,266(2):147-173.
  • 10Dodeigne C,Thunus L,Lejeune R.Chemiluminescence as a Diagnostic Tool. A review [J].Talanta.2000,51(3):415-439.

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