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卟啉类有机体系THP/PMMA的永久性光谱烧孔 被引量:5

Persistent spectral hile-burning of the organic system THP/PMMA
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摘要 首次报道了四-对羟基苯基卟吩/有机玻璃体系(THP/PMMA)的单光子永久性光谱烧孔.研究了烧孔特性和成孔条件.测量了孔的稳定性,在液氦温度下孔的保存时间已超过几个小时.实现了孔的擦除和重复烧孔.探讨了烧孔机制,认为激光诱导质子转位变构是导致该体系永久性光谱烧孔的原因. One-photon persistent spectral hole-burning was reported for the organic guest molecule 5, 10, 15, 20-tetra-(p-hydroxyphenyl) prorphin (THP) doped into a poly (methylmethaorylate) (PMMA) amorphous matrix at liquid helium temperature. Hole properties and conditions for hole formation were investigated. Laser induced tautomerization was believed responsible for the hole burning. Stability of the holes was demonstrated longer than hours. Hole erasing and repeatable hole burning were realized.
出处 《光学学报》 EI CAS CSCD 北大核心 1992年第4期336-341,共6页 Acta Optica Sinica
关键词 光谱烧孔 THP/PMMA 永久烧孔 persistent spectral hole-burning, THP/PMMA, laser induced tautome-rization.
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