LiCl-NiCl_2熔盐体系相图

Phase Diagram of LiCl-NiCl_2 System

用原子参数 模式识别方法研究AX BX2 型卤化物熔盐体系形成固溶体的规律性 ,同时预报了LiCl NiCl2 熔盐体系能形成以LiCl为基的广泛固溶体。采用热分析法和X 射线衍射分析等实验测定了LiCl NiCl2熔盐体系相图 ;结果与计算预报相符。

The regularities and criterion of the formation of solid solutions for AX-BX 2-type of binary halide systems have been investigated by atomic parameter-pattern recognition method.The LiCl-NiCl 2 system is predicted to be the extensive solid solution.The results of computerized prediction for LiCl-NiCl 2 system accord with our own experimental results by DTA and X-ray analysis.