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用PH/S电极对在酸性介质中测定炼油污水的硫离子

Determination of the Total Number of Sulfide Ions in the Waste Water from Petroleum Refinery with PH/S Electrodes in Acid Media
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摘要 本文用普通的单高阻输入离子计和PH/S电极对,在酸性介质中测定炼油污水的硫离子,无需使用PH缓冲液。电极线性范围10^(-3)—5×10^(-8)mol/L,相对标准偏差<5%,加标回收率95—102%与电位滴定法测定结果一致。 An experiment for determination of the total number of sulfide ions in the waste water from petroleum refinery with a single high input impedance ion meter and with a pH glass electrode and a sulfide electrode in acid media is described. The electrode exhibits Nernstion response, relative standard deviation and recovery are 5×10^(-8)—10^(-3), <5% and 95-102% respectively. These results show good agreement as compared with assays for sulfide ion using electric potential titration method and titer method.
作者 张志翔
出处 《广州化工》 CAS 1992年第2期65-66,共2页 GuangZhou Chemical Industry
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