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二硫代草酸根桥联一维锰(Ⅱ)配合物的合成和磁性 被引量：4

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摘要 以1,2-二硫代草酸根(以下简称为Dto)作为桥联基团,合成了3个锰(Ⅱ)的配合物[Mn(L)Dto],其中L=Phen(1),Bpy(2)和en(3).研究表明,这3个配合物的结构极其相似,都是Dto桥联的一维链状结构.对配合物1的变温磁化率的研究表明,在配合物中Mn(Ⅱ)离子间存在弱的反铁磁相互作用.
作者 崔建中 师唯 程鹏 陈绪芳 廖代正 阎世平 姜宗慧 王耕霖
机构地区 南开大学化学系
出处 《科学通报》 EI CAS CSCD 北大核心 2003年第4期335-337,共3页 Chinese Science Bulletin
基金 国家自然科学基金(批准号:90101028 50173011) 天津市自然科学重点基金(批准号:013801611) 教育部优秀青年教师教学科研奖励计划资助项目.
关键词 合成 1 2-二硫代草酸根 ESR 磁性 配位化学 变温磁化率 一维锰配合物
分类号 O641.4 [理学—物理化学]
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参考文献11

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同被引文献42

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科学通报
2003年 第4期

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