期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

水溶性杯[4]芳烃衍生物与稀土钐[III]离子形成配合物的光谱特性 被引量：2

Spectroscopic properties on the formation complex of water solublecalix[4]arene derivative with earth samarium (III) ion
下载PDF
导出
摘要 水溶性杯[4]芳烃(L4)可以与Sm3+形成能量传递配合物,但是能量传递效率较低,Sm3+的红光发射较弱,而且配合物溶液浓度增大时还发生自猝灭现象。根据配体第一激发态和第一激发三重态能级分布,比较Sm3+、Eu3+、Tb3+等稀土离子4f能级,可以合理地解释这种现象。 The spectroscopic properties on formation complex of 25,26,27,28-tetra-carboxylic acid-5,11,17,23-calix［4］arenesulfonate (L\-4) and samarium (III) ion was investigated by UV-Vis and fluorescence measurements. L\-4 can form an energy transfer complex with Sm\+\{3+\}, but the fluorescence of L\-4·Sm\+\{3+\} is not strong and easily quenched by itself. The energy transfer mechanism from ligand to rare earth ions was also discussed.
作者 张宁 李伟 唐世华
机构地区 驻马店师专化学系
出处 《河南科学》 2003年第2期152-154,共3页 Henan Science
关键词 芳烃衍生物 光谱特性 钐配合物 能量传递 荧光特性 能级分布 water-soluble calix[4]arene samarium complex energy transfer fluorescence property
分类号 O614.337 [理学—无机化学] O657.3 [理学—分析化学]
  • 相关文献

参考文献1

二级参考文献13

  • 1Sabbatini N., Guardigli M., Mecati A.et al..J. Chem. Soc., Chem. Commun.[J], 1990: 878-879
  • 2Sato N., Shinkai S.. J. Chem. Soc., Perkin Trans. 2[J], 1993: 621-624
  • 3Matsumoto H., Ori A., Inokuchi F.et al..Chem. Lett.[J], 1996: 301-302
  • 4Steemers F. J., Verboom W., Reinhoudt D. N.. J. Am. Chem. Soc.[J], 1995, 117: 9 408-9 414
  • 5Rudkevich D. M., Verboom W., Reinhoudt D. N.et al..J. Chem. Soc., Perkin Trans. 2[J], 1995: 131-134
  • 6Steemers F. J., Meuris H. G., Verboom W.et al..J. Org. Chem.[J], 1997, 62: 4 229-4 235
  • 7Atwood J. L., Orr G. W., Mean N. C.et al..Inorg. Chem.[J], 1997, 31: 603-606
  • 8Shinkai S., Mori S., Koreishi H.et al..J. Am. Chem. Soc.[J], 1986, 108: 2 409-2 416
  • 9Sato N., Yoshida I., Shinkai S.. Chem. Lett.[J], 1993: 1 261-1 264
  • 10Saito S., Hoshino H., Yotsuyanagi T.. Bull. Chem. Soc. Jpn.[J], 2000, 73: 1 817-1 821

共引文献5

同被引文献44

  • 1余晓冬,王凯.新型水溶性杯[4]芳烃的合成和性质研究[J].化学通报,2007,70(8):613-616. 被引量：9
  • 2Panigrahi B S,Mathews C K,Viswanathan K S,Peter S.Fluorescence enhancement and eofluorescence in complexes of terbium,dysprosium and europium with trimesic acid[J].Analytical Chimica Acta,1993,282:1.
  • 3Zhang N,Tang S H,Liu Y.Luminecscnce behavior of a water soluble calix[4]arene derivatives complex with terbium ion(Ⅲ)in gelation solution[J].Spectrochimica Acta Part A,2003,59:1107-1112.
  • 4Shinkai S,Mori S,Koreishi H et a1.Hexasulfonated calix[6]arene derivatives:a new class of catalysts,surfactants,and host molecules[J].J.Am.Chem.Soc.,1986,108:2409—2416.
  • 5Stein G,Wtirzberg E.Energy gap law in the solvent isotope effect on radiationless transitions of rare earth ions[J].J.Chem.Phys.,1975,62:208—213.
  • 6陆国弟,刘东祥,朱志良,施宪法,陈与德.杯芳烃的配位化学Ⅶ.水溶性杯[8]芳烃与过渡元素配合物的热力学研究[J].无机化学学报,1997,13(1):28-31. 被引量：5
  • 7Makha M,Colin L Raston.Synthesis of p-benzylcalix[4]arene and its sulfonated water soluble derivative[J].Chemical Communications,2001(23):2 470-2 471.
  • 8Perret F,Stéphanie G,Suwinska K,et al.One methylene too far:The solid state structure of the para-sulfonatomethylcalix[4]arene[J].Journal of molecular structure,2007,830(1):35-39.
  • 9Iki Nobuhiko,Toyohisa F,Sotaro M.Anew water-soluble host molecule derived from thiacalixarene[J].Chemistry Letters,1998:625-626.
  • 10Xiong Kecai,Jiang Feilong,Wu Mingyan,et al.Two novel chains based on capsules supported by water-soluble calixarenes and metal complexes[J].Journal of Solid State Chemistry,2012,192:215-220.

引证文献2

二级引证文献7

河南科学
2003年 第2期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部