电子填充、电离的真实顺序与最大结合能模型(Ⅱ)

REAL ORDERS OF ELECTRON OCCUPYING AND IONIZATION WITH THE LARGEST COMBINING ENERGY MODEL(Ⅱ)

本文根据保利原理和能量最低原理,提出了填充核外电子的最大结合能模型,用玻恩-哈伯循环图、一元二次不等式法解决了电子填充和电离的真实顺序;用竞争组态能量差法研究了洪特规则的特例。还对Tc、Ir^+、Pt的电子组态进行了讨论。

According to Paulis and the lowest energy principles,we have obtained the largest combining energy model for electron oceupying outer nuclear.By using of Born-Haber's tnermochemical cyele and one unknown seconu power ineq- uality,the real orders of electron occupying and ionization have been solved. With the method of energy difference of competitive configurations, the special cases of Hund's rules have studied. The electron configurations of Tc,Ir^+and Pt have been also discussed.