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PVP为模板控制合成球形碳酸钙 被引量:25

Template Induced Synthesis of Spherical CaCO_3 by Polyvinylpyrrolidone
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摘要 Spherical calcium carbonate was prepared by the reaction of sodium carbonate with calcium chloride at the presence of a protein like molecule, polyvinylpyrrolidone, as the template. The products were characterized by elemental analyses, XRD, SEM, and TG DSC respectively. The effects of polyvinylpyrrolidone on the crystal form and morphology of the as prepared CaCO3 were investigated. It was found that the aggregative shape of the produced calcium carbonate crystalline could be well controlled by adjusting the concentration of the polyvinylpyrrolidone template. This may be of important meanings to the biomimetic synthesis of novel inorganic materials. Spherical calcium carbonate was prepared by the reaction of sodium carbonate with calcium chloride at the presence of a protein-like molecule, polyvinylpyrrolidone, as the template. The products were characterized by elemental analyses, XRD, SEM, and TG-DSC respectively. The effects of polyvinylpyrrolidone on the crystal form and morphology of the as-prepared CaCO3 were investigated. It was found that the aggregative shape of the produced calcium carbonate crystalline could be well controlled by adjusting the concentration of the polyvinylpyrrolidone template. This may be of important meanings to the biomimetic synthesis of novel inorganic materials.
机构地区 浙江大学化学系
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2003年第4期445-448,共4页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.20171039)
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