数学方法在滴定量热法测量配合体系热力学函数中的应用

Mathematical Methods Applied in the Detection of Coordination Reaction's Thermodynamic Functions by Calorimetry

通过对配合体系一次滴定所得的量热图谱进行数学处理的方法 ,可同时得出目标反应的平衡常数和热力学函数 ,具有方法简便

By mathematical methods, we have established a method how to measure targeted reaction's balanced constant and thermodynamic functions through the graphic of a titration calorimetric graph. This method posses its own advantages such as good accuracy and simple operation.