摘要
本文提出了一个新的热化学闭路循环分解制氢的四段法.应用正交试验对影响反应收率的主要因素进行了实验.利用最小二乘方法和多元回归对实验数据进行了处理并获得了四个数学模型、利用X-射线粉末衍射对反应的中间固态物质进行了检测.研究了循环中反应的机理.
A new four-step closed-cyele thermochemieal process for the generation of hydrogen and ocygen fron water is described. Main factors inflreneing the yields of the produects from these reactions are iavest igated by carrying oat experiments arranged according to orthographic design. The experimental data are treated by means of least square method and multicomponent regression. Four mathematical models are derived. The presence of the intermediate prolaets are leteeted by Kerty powder diffractioa. Mechanisms of these reactions are studied.
关键词
热化学
制氢
闭路循环
thermochemical
elosed-eycle
produetion of Hydro