期刊文献+

电化学无模板合成直立有序聚苯微米管 被引量:2

原文传递
导出
摘要 在体积比为1︰2的三氟乙酸(TFA)与三氟化硼乙醚(BFEE)混合溶液中, 以十二烷基苯磺酸钠(SDBS)为表面活性剂, 用电化学方法对苯进行氧化聚合合成了直径为0.2~0.8 μm, 长约10 μm直立有序的聚苯(PPP)微米管. 用扫描电子显微镜(SEM)和透射电子显微镜(TEM)观察了微管的形貌, 用拉曼光谱对微管的结构进行了表征. 实验结果表明: 电极材料的性质、单体与表面活性剂的摩尔比和聚合电压等因素对PPP微米管的形成有着重要的影响.
出处 《科学通报》 EI CAS CSCD 北大核心 2003年第1期35-37,共3页 Chinese Science Bulletin
基金 国家自然科学基金资助项目(批准号:50133010 50073012)
  • 相关文献

参考文献15

  • 1[1]Skotheim T A, Elsembaumer R L, Reynocds J K, et al. Handbook of Conducting Polymers. New York: Marcel Dekker, 1998. 213~264
  • 2[2]Phani K L N, Pitechumani S, Ravichandran S, et al. Microemulsion- based electrosynthesis of polyparaphenylene. J Chem Soc Chem Commun, 1993(2): 179~181
  • 3[3]Goldenberg L M, Aeiyac S, Lacaze P C. Electropolymerization of benzene in two-phase benzene/acid system: Comparative study in strong proton acid and superacid media. J Electroanal Chem, 1992, 327(1-2): 173~184
  • 4[4]Goldenberg L M, Aeiyanc S, Lacaze P C. Low potential anodic polymerization of benzene in strong acid and superacid solutions. J Electroanal Chem, 1992, 335(1-2): 151~161
  • 5[5]Li C, Chen F E, Shi G Q, et al. Electrochemical synthesis of free-standing PPP film in mixed electrolytes of trifluoride and trifluoacetic acid. J Appl Polym Sci, 2002, 83(11): 2462~2466
  • 6[6]Pool R. Anyon superconductivity. Science, 1990, 47(4949): 1410
  • 7[7]Martin C R. Nanomaterials: a membrane-based systhetic approach. Science, 1994, 266: 1961~1966
  • 8[8]Fu M X, Zhu Y H, Tan R Q, et al. Aligned polythiophene micro- and nanotubules. Adv Mater, 2001, 13: 1874~1877
  • 9[9]Yang Y S, Wan M X. Microtubules of polypyrrole synthesized by an electrochemical template-free method. J Mater Chem, 2001, 11: 2022~2027
  • 10[10]Qiu H J, Wan M X, Matthews B, et al. Conducting polyaniline nanotubes by template-free polymerization. Macromolecules, 2001, 34(4): 675~677

同被引文献125

  • 1Taiqi LIUSchool of Materials and Chemical Engineering, Beijing Institute of Petro-chemical Technology, Beijing 102617, China.Preparation of a Novel Micro/nano Tubes via Electrospun Fiber as a Template[J].Journal of Materials Science & Technology,2004,20(5):613-616. 被引量:4
  • 2Kim E, Xia Y N, Whitesides G M. Polymer microstructures formed by molding in capillaries. Nature, 1995, 376(6541): 581~584.
  • 3Kim E, Xia Y N, Zhao X M, et al. Solvent-assisted microcontact molding: A convenient method for fabricating three-dimensional structures on surfaces of polymers. Adv Mater, 1997, 9(8): 651~654.
  • 4Yuan J Y, Qu L T, Shi G Q, et al. Linear attangement of polypyrrole microcontainers. Chem Commun, 2004, (8): 994~995.
  • 5Qin D, Xia Y N, Rogers J A, et al. Microfabrication, microstructures and Microsystems. Microsystem technology in chemistry and life science. Topics in Current Chemistry, 1998, 194: 1~20.
  • 6Choi S J, Park S M. Electrochemical growth of nanosized conducting polymer wires on gold using molecular templates. Adv Mater, 2000, 12(20): 1547~1549.
  • 7Jerome C, Jerome R. Electrochemical synthesis of polypyrrole nanowires. Angew Chem Int Ed, 1998, 37(18), 2488~2490.
  • 8Huang L M, Wang Z B, Wang H T, et al. Polyaniline nanowires by electropolymerization from liquid crystalline phases. J Mater Chem, 2002, 12(2): 388~391.
  • 9Goren M, Qi Z G, Lennox R B. Selective templated growth of polypyrrole strands on lipid tubule edges. Chem Mater, 2000, 12(5): 1222~1228.
  • 10Shiratori S S, Mori S, Ikezaki K. Wire bonding over insulating substrates by electropolymerization of polypyrrole using a scanning micro-needle. Sensors and Actuators B, 1998, 49(1-2): 30~33.

引证文献2

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部