氢醌卟啉的合成及其对醌的分子识别

Synthesis of porphyrin-hydroquinone and study of molecular recognition to quinone

利用氢醌与2 硝基卟啉直接反应,合成了2 (2 ,5 二羟基苯基) 5,10,15,20 四苯基卟啉,并利用紫外光谱、荧光光谱、电化学方法考察了它们对醌的分子识别,结果显示2 (2 ,5 二羟基苯基) 5,10,15,20 四苯基卟啉对醌具有较好的识别能力。

2(2,5dihydroxyphenyl)5,10,15,20tetraphenylporphyrin were synthesised by direct reaction of hydroquinon with 2nitroporphyrin.Their recognition to quinones were investigated by using UVVis spectroscopic,fluorescence spectroscopic and electrochemical methods.It was that 2(2,5dihydroxyphenyl)porphyrin had selective recognition to quinone.