摘要
利用氢醌与2 硝基卟啉直接反应,合成了2 (2 ,5 二羟基苯基) 5,10,15,20 四苯基卟啉,并利用紫外光谱、荧光光谱、电化学方法考察了它们对醌的分子识别,结果显示2 (2 ,5 二羟基苯基) 5,10,15,20 四苯基卟啉对醌具有较好的识别能力。
2(2,5dihydroxyphenyl)5,10,15,20tetraphenylporphyrin were synthesised by direct reaction of hydroquinon with 2nitroporphyrin.Their recognition to quinones were investigated by using UVVis spectroscopic,fluorescence spectroscopic and electrochemical methods.It was that 2(2,5dihydroxyphenyl)porphyrin had selective recognition to quinone.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2003年第2期215-217,共3页
Chemical Research and Application
基金
国家自然科学基金资助项目(29872033)