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Ni基六铝酸镧LaNiAl_(11)O_(19)催化剂表面甲烷CO_2的重整积炭速率 被引量:2

Study on rate of deposited carbon over Ni base hexaaluminate LaNiAl_(11) O_(19) catalyst during CO_2 reforming of methane
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摘要 In this paper,the kinds and amount of carbon deposited over Ni base hexaaluminate LaNiAl 11 O 19 catalyst,after both CH 4 decomposition and CO 2 reforming of methane,was determined by means of X ray photoelectron spectroscopy (XPS) and thermogravimetric analysis(TGA) techniques,respectively.Over the catalyst,the rates of carbon deposited vs reaction time were also investigated during the reaction.Two carbon forms were produced,and graphitic carbon was the main and inactive carbon. In this paper,the kinds and amount of carbon deposited over Ni base hexaaluminate LaNiAl 11 O 19 catalyst,after both CH 4 decomposition and CO 2 reforming of methane,was determined by means of X ray photoelectron spectroscopy (XPS) and thermogravimetric analysis(TGA) techniques,respectively.Over the catalyst,the rates of carbon deposited vs reaction time were also investigated during the reaction.Two carbon forms were produced,and graphitic carbon was the main and inactive carbon.
出处 《化学研究与应用》 CAS CSCD 北大核心 2003年第2期249-250,256,共3页 Chemical Research and Application
基金 国家自然科学基金资助项目(29973012)
关键词 镍基六铝酸镧 LaNiAlllO19 催化剂 甲烷 C02 重整 积炭速率 二氧化碳 合成气 表面积炭 Methane carbon dioxide carbon deposition X ray photoelectron spectroscopy thermogravimetric analysis
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