芳醛缩-4-烯丙基-3-硫代氨基脲的合成与表征

Synthesis and Characterization of Aromatic-4-Allyl-3-Thiosemicarbazone

由芳醛与4-烯丙基-3-硫代氨基脲缩合制得了两种含硫Schiff碱配体.此类配体在有机溶剂中有较大的溶解度,与过渡金属离子形成的配合物在有机溶剂中亦有较好的溶解性.

Two kinds of new Schiff base containing thiocarbamide group were synthesized by condensation of the substituted aromatic aldehydes with 4-allyl-3-thiosemicarbazone.The structures of these compounds were confirmed by IR,1 H NMR and E.A..The solubility of these ligands in organic solvents is pretty good and the complexation behavior of these ligands with some transition metals under different conditions was briefly investigated.