用前线轨道理论判断周环反应规律的简单方法

A CONVENIENT METHOD WITH FRONTAL ORBIT THEORY TO PREDICT THE LAW OF PERICYCLIC REACTION

归纳了开链共轭多烯的 π分子轨道位相变化规律 ,采用了一种简便的判断前线轨道位相的方法 ,用于判断周环反应及其立体化学 .

This paper induces the rule of π-molecule orbital phase change in chain conjugated polyenes. The rule applies a simple method of judging the frontier orbital phase to predicting the results pericyclic reactions and the concerted stereochemical reactions.