钛硅分子筛TS-1合成及催化环己酮氨氧化的研究进展

Advances in TS-1 molecular seive synthesis and ammoximation of cyclohexanone catalyzed by TS-1

钛硅分子筛TS- 1催化的环己酮氨氧化反应是一个绿色过程。介绍了TS- 1分子筛的合成、TS- 1分子筛催化的环己酮氨氧化及环己酮氨氧化与过氧化氢生产的集成。指出提高催化剂的性能、降低其生产成本是今后研究的重点 。

The ammoximation of cyclohexanone with H 2O 2 and ammonia catalyzed by titanium silicalite 1 (TS 1) is an environment friendly process.The research progress in TS 1 synthesis,ammoximation of cyclohexanone and the integrated process of cyclohexanone oxime production are introduced.It is indicated that improving the physical properties of the catalyst and reducing the cost of production are major work to be done,the integrated process of H 2O 2 production and ammoximation of cyclohexanone should be attached with great importance to green chemical industry.