摘要
为有效防治吕家坨5424Z采煤工作面含水煤自燃,通过采用差示扫描量热技术(DSC)与程序升温相结合的方法,分析了不同含水量对煤样吸、放热参数的影响规律。研究表明:水分增量在1%~9%范围内,其热流差零值点温度普遍较高,说明煤样不易发生自燃现象。但在煤样水分增量为1%~4%时,其吸收峰峰值温度较低,且此时吸热速率达到最值,这部分煤样与其他实验水分段相比较易发生自燃现象。随着煤样含水量增大,其产生的CO、CO2的量也逐渐增大,但是差别不明显,说明对煤层增加1%~7%含水量时,能适当促进煤升温氧化、自燃的过程。
To effectively control the spontaneous combustion of water-bearing coal in 5424 Z coal mining face of Lyujiatuo Coal Mine,the influence of different water contents on the adsorption and exothermic parameters of coal samples was analyzed by using differential scanning calorimetry(DSC)and temperature programming method.The research shows that the moisture increase is in the range of 1%to 9%,and the temperature difference of the zero point of the heat flow is generally higher,indicating that the coal sample is not prone to spontaneous combustion.However,when the moisture increase of coal sample is 1%to 4%,the peak temperature of absorption peak is lower,and the heat absorption rate reaches the maximum value at this time.This part of coal sample is more prone to spontaneous combustion than other experimental water sections.As the water content of coal samples increases,the amount of CO and CO2 produced by them increases gradually,but the difference is not obvious.This indicates that when the water content of coal seam is increased by 1%to 7%,the process of warming oxidation and spontaneous combustion of coal can be appropriately promoted.
作者
张九零
朱壮
范酒源
朱定
刘春雨
ZHANG Jiuling;ZHU Zhuang;FAN Jiuyuan;ZHU Ding;LIU Chunyu(Mining Engineering College,North China University of Science and Technology,Tangshan 063009,China)
出处
《煤矿安全》
CAS
北大核心
2019年第7期42-45,共4页
Safety in Coal Mines
基金
国家自然科学基金资助项目(51504077,51404086)
河北省自然科学基金资助项目(E2016209056)
华北理工大学杰出青年基金资助项目(jp201509,JQ201710)
关键词
煤自燃
含水量
差式扫描量热法
放热速率
程序升温
吸氧量
coal spontaneous combustion
water content
differential scanning calorimetry
heat release rate
temperature programming
oxygen uptake