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C3馏份选择加氢催化精馏工艺及其催化剂的研究 被引量:2

Study on the process of C3 fraction catalytic hydrogenation with distillation and its catalyst
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摘要 对C3馏份选择加氢催化剂及工艺条件进行了研究,试验结果表明,含有3.17%(物质的量的含量)丙炔和丙二烯的C3馏份经催化精馏加氢,塔顶C3馏份中的炔烃、二烯烃可脱至≤10μg/g,丙烯收率≥102%。经262h考核,催化剂仍保持良好的活性和选择性。 The selective hydrogenation catalyst and process conditions for the C3 fraction are studied. The results show that 3.17%( mole) of MA PD in feed could be removed to 10μg/g, the yield of propylene is higher than 102%. The catalyst activity and selectivity is perfect for 262 h.
出处 《化学工业与工程技术》 CAS 2003年第2期18-20,共3页 Journal of Chemical Industry & Engineering
关键词 催化精馏 C3馏份 丙炔 丙二烯 选择加氢 催化剂 Catalytic distillation C3 fraction Methyl acetylene Propadiene Selective hydrogenation Catalyst.
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参考文献2

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同被引文献28

  • 1李庆国,史建公,尹国海,张敏宏,缪清元,张毅.国内乙烯装置丙烯加氢精制工艺研究进展[J].中外能源,2012,17(4):79-85. 被引量:1
  • 2陈得文,张宝泉,顾惠新,高玉林.丙烯精制系统的改造[J].石化技术与应用,2005,23(6):453-455. 被引量:8
  • 3赵炳义 刘新香.碳三液相选择加氢除丙炔和丙二烯催化剂的研究.石油化工,1987,16(12):821-827.
  • 4中国石油化工股份有限公司,中国石油化工股份有限公司北京化工研究院.一种用于烯烃生产装置的催化精馏方法:中国,1274649A[P].2006-09-13.
  • 5Catalytic Distillation Technologies. Process for the Removal of MAPD from Hydrocarbon Streams: US, 6414205 [P]. 2002- 07-02.
  • 6Catalytic Distillation Technologies. Selective Hydrogenation of Acetylenes and Dienes in a Hydrocarbon Stream: US, 7368617 [P]. 2008-05-06.
  • 7王松汉.乙烯装置技术与运行[M]北京:中国石化出版社,2009652-662.
  • 8赵炳义;刘新香.碳三液相选择加氢除丙炔和丙二烯催化剂的研究[J]石油化工,1987(12):821-827.
  • 9Catalytic Distillation Technologies. Process for the Removal of MAPD from Hydrocarbon Streams[P].US,6414205,2002.
  • 10Catalytic Distillation Technologies. Selective Hydrogenation of Acetylenes and Dienes in a Hydrocarbon Stream[P].US,7368617,2008.

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