卟啉化合物的合成及其对细胞色素P-450的模拟 Ⅵ 金属卟啉催化的仿生氧化反应中的溶剂效应

SYNTHESIS OF PORPHYRIN COMPOUNDS AND BIOMIMESIS FOR CYTOCHROME P-450——Ⅵ.SOLVENT ON THE IMITATIC OXIDATION CATALYZED BY METALLOPORPHYRINS

本工作分别以TPPFe^(111)CI、TPPMn^(111)Cl、[TPPFe^(111)]_2O和[TPPMn^(111)]_2O作为细胞色素P-450模型化合物在温和条件下催化PhIO向环己烷转移一个氧原子的反应,研究了这些反应在不同溶剂中的反应动力学行为以及溶剂效应对反应速率,反应产率和产物选择性的影响.

This work reported the reactions of transferring an oxygen atom from PhIO tocyclohexane under room temperature and atomsphere catalyzed by TPPMn^(III)Cl,TPPMn^(III)Cl,[TPPFe^(III)]_2O and[TPPMn^(III)]_2O resperctively.The kinetic properties and the solvent effects onthe rates,yields and selectivies of the reactions were studied.