摘要
本文首先发现了硫醇在相当于引发剂用量范围内,在常温下能够诱发甲基丙烯酸甲酯与丙烯腈的共聚反应.并研究了该共聚反应的动力学、聚合物组成及分子量等有关问题.
In this work,the authors found that thiol is capable of initiating the copol-ymerization of methyl methacrylate (MMA) and acrylonitrile (AN) at room temperature. The copolymerization kinetics、copolymer composition and molecular weight of the copolymer were studied.
关键词
丙烯腈
甲基
丙烯酸甲酯
共聚
2-methyl-2-undecanethiol
methyl methaoylate
acrylonitrile
copolymerization.
