Au(PPh_3)_nX(X=Cl,Br,I)的电化学合成

Preparation of Au(PPh_3)_nX(X=Cl,Br,I) by electrosynthesis

以Au、PPh3、NH4X(或I2)为原料,通过电化学方法合成得到Au(PPh3)nX(X=Cl,Br,n=1;X=I,n=2)配合物.研究了电合成机理,讨论了电解电压对电化学效率的影响.I2作为反应原料,为Au(PPh3)nI的合成提供了新的途径.

Some complexs of Au(PPh3)nX(X=Cl,Br,I)were electrosynthesized using NH4X or I2 in nonaqueous medium.This method is better than the traditional chemical synthesis.The influence of voltage on Ef was studied.